Thermoplastic mouldable composition
专利摘要:
There is described a thermoplastic, transparent moulding material comprising 1 - 99 per cent by weight of at least one cellulose esterified with one or more aliphatic carboxylic acids and 99 - 1 per cent by weight of an ethylene-vinyl ester copolymer comprising 30 - 98 per cent by weight of built-in vinyl ester. A further thermoplastic moulding material comprises 50 - 98.99 per cent by weight of at least one cellulose esterified with one or more aliphatic carboxylic acids, 1 - 50 per cent by weight of an ethylene-vinyl ester copolymer comprising 60 - 98 per cent by weight of built-in vinyl ester and 0.01 - 20 per cent by weight of a low molecular weight plasticiser, the sum of 1) - 3) adding to 100 per cent by weight. Finally there is also described a moulding material comprising 95 - 70 per cent by weight of at least one cellulose esterified with one or more aliphatic carboxylic acids and 5 - 30 per cent by weight of an ethylene-vinyl acetate copolymer comprising 30 - 98 per cent by weight of built-in vinyl acetate. The moulding materials described can be used for producing shaped articles such as acetate filament, block acetate, safety film bases, electrical insulation films and packaging films. 公开号:SU828976A3 申请号:SU752140025 申请日:1975-05-29 公开日:1981-05-07 发明作者:Элабд Эльгани Салах;Фишер Винфрид;Принц Рихард 申请人:Байер Аг (Фирма); IPC主号:
专利说明:
Table 1 n-impact viscosity according to standard DiN 53453; Dk is the impact viscosity of the sample with a groove but the standard is DiN 53 453; Vicat - tsmnsratura soften Vicat but to the standard DiN 53460 method B (power: 49.05 n); with/,/,-. - limit of yield strength when bent to DIN 53452; / - NrOGPb NRI G. HK-30 is a hardness of 24 h with a sharnlom of 30 s, but the standard is DiN 53456. Transparency: + means opacity similar to glass; - means nenoozpachnost. Note to the table. 2 cm. In table. one. Table 2
权利要求:
Claims (1) [1] The claims 25 A thermoplastic molding composition based on cellulose ester and a polymer modifier, characterized in that, in order to increase 30 frost resistance, the composition contains cellulose acetate butyrate cellulose with a content of butyric acid groups of 42–46% and acetate groups of 18–21%, acetopropionate cellulose with a content of propionic acid groups of 54–58% and acetate groups of 5–8% or secondary cellulose acetate, and as a modifier, a copolymer of ethylene with vinyl acetate with a content of vinyl acetate of 8–78% and a molecular 50000- 350000 th weight the following component ratio, wt. %: Cellulose Ester 75-95 Modifier 5-25 Source of information taken into account during the examination: 1. USSR Copyright Certificate λ ”292990, cl. C 08 L 1/10, published. 1971 (prototype).
类似技术:
公开号 | 公开日 | 专利标题 SU828976A3|1981-05-07|Thermoplastic mouldable composition JPS63245428A|1988-10-12|Production of thermoplastic resin composition US3943190A|1976-03-09|Process for preparing acrylate polymers Imai et al.1961|The effect of stereoregularity on the polyvinyl alcohol–iodine reaction KR910018502A|1991-11-30|Thermosetting resin composition KR890008184A|1989-07-10|Optical material ES442631A1|1977-04-16|Plastisol of an organic polymer and a plasticiser KR970707232A|1997-12-01|IMPROVED PROCESS FOR PREPARING ETHYLENE COPOLYMER PLASTICIZED PVC - Patent application GB1361842A|1974-07-30|Polyester compositions JPS56139551A|1981-10-31|Transparent, easily slipping polyethylene terephthalate film US2492203A|1949-12-27|Esters of methacrylic acid US2883361A|1959-04-21|Light stable composition containing a blend of a synthetic rubber and a salicylate polymer KR890701694A|1989-12-21|Polyamide compositions impervious to fluorocarbons and hydrocarbons GB1002901A|1965-09-02|Improvements in or relating to vinyl aromatic polymer compositions CA1026032A|1978-02-07|Moulding compositions based on unsaturated polyesters, copolymerisable vinyl monomers and cellulose esters CA994043A|1976-07-27|Caulking composition comprising polymer having addition polymerized backbone having carboxyl groups esterified with drying oil fatty acid glycidyl ester JPS5630405A|1981-03-27|Preparation of hydrophilic, water-insoluble fine particle US4097429A|1978-06-27|Thermoplastically processible moulding compound of cellulose esters and ethylene/vinyl esters copolymers KR920021597A|1992-12-18|Polymeric latexes from vinyl acetate and vinyl esters of branched carboxylic acids and methods for their preparation JPH02140243A|1990-05-29|Glittering plastic JPS5730745A|1982-02-19|Adherent resin composition SU1407936A1|1988-07-07|Polymeric compound GB1356624A|1974-06-12|Liquid coating composition KR920021598A|1992-12-18|Polymeric latexes from vinyl acetate and vinyl esters of branched carboxylic acids and methods for their preparation IE42764L|1977-06-30|Curable composition comprising a dissolved polymer
同族专利:
公开号 | 公开日 NO143911C|1981-05-06| CH617948A5|1980-06-30| DE2426178A1|1975-12-18| NO751730L|1975-12-02| NL183241C|1988-09-01| JPS5845458B2|1983-10-11| FR2275514B1|1979-04-13| DD119249A5|1976-04-12| NL7506381A|1975-12-02| DE2426178B2|1980-10-30| BE829578A|1975-11-28| AT343918B|1978-06-26| FR2275514A1|1976-01-16| ES438015A1|1977-05-16| SE411354B|1979-12-17| BR7503381A|1976-04-27| SE7506095L|1975-12-01| GB1501414A|1978-02-15| NO143911B|1981-01-26| ATA402175A|1977-10-15| DE2426178C3|1981-12-03| DK238275A|1975-11-30| IT1035896B|1979-10-20| JPS512756A|1976-01-10| AU8157375A|1976-12-02| CA1071786A|1980-02-12|
引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题 US2186454A|1937-06-24|1940-01-09|Hercules Powder Co Ltd|Lacquers containing cellulose acetobutyrate and cellulose acetopropionate| US3454349A|1965-12-28|1969-07-08|Celanese Corp|Cellulose ester shaped articles of improved dyeability| DE1745565A1|1967-10-23|1971-10-28|Wacker Chemie Gmbh|Process for the production of copolymers from ethylene and vinyl esters| JPS50759B1|1969-03-20|1975-01-11| US3682850A|1970-07-30|1972-08-08|Du Pont|Cellulosic esters of two organic acids blended with a copolymer of ethylene and at least one ethylenically unsaturated ester of a saturated fatty acid| JPS5343978B2|1973-12-04|1978-11-24|DE2807663A1|1978-02-23|1979-08-30|Bayer Ag|USE OF MIXTURES OF CELLULOSE STARS AND ETHYLENE-VINYL ACETATE COPOLYMERS IN CONTACT EYE OPTICS| CA1163739A|1980-07-12|1984-03-13|Dietrich J. Bahr|Process for producing a polymerized, heat-resistantlacquer| JPH0741056B2|1986-03-14|1995-05-10|松下電工株式会社|Matsusage machine| JPS6326462A|1986-07-16|1988-02-04|Sumitomo Heavy Ind Ltd|Support mechanism for pulley of grinding stone driving motor| JP5182778B2|2006-06-12|2013-04-17|太平化学製品株式会社|Resin composition and transparent sheet| JP5258233B2|2006-09-07|2013-08-07|太平化学製品株式会社|Resin composition and molded body| JP6511754B2|2014-09-26|2019-05-15|富士ゼロックス株式会社|Resin composition and resin molded body| JP6897196B2|2016-08-31|2021-06-30|富士フイルムビジネスイノベーション株式会社|Resin composition and resin molded product| JP2019534367A|2016-11-11|2019-11-28|イーストマン ケミカル カンパニー|Polymer-based resin compositions derived from cellulose and articles made using these compositions| CN110168006A|2016-11-11|2019-08-23|伊士曼化工公司|Cellulose esters and ethane-acetic acid ethyenyl ester composition and the product manufactured using these compositions|
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申请号 | 申请日 | 专利标题 DE2426178A|DE2426178C3|1974-05-29|1974-05-29|Thermoplastic molding compounds made from cellulose esters and ethylene-vinyl ester copolymers| 相关专利
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